The output of generator having 120 degree phaseshift. Ever time the instantaneous magntiude will be root 3 times the phase voltage. The magnitude will be same. While measuring we are considering the two phases which is maximum.
The Phase voltage of an generator is 220 - 230 V but the Phase to phase
voltage (Line Voltage) will be 400 V.
Voltage of
R - Phase-230
Y - Phase-230
B - Phase-230
but
RY-400V
BY-400V
...